By Anne George
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C. & Iacono, V. J. (1998). Variability of hydroxyapatite-coated dental implants. Int. J. Oral. Maxillofac Implants, 13, 601-610. Gross, K. ; Ray, N. & Rokkum, M. (2002). The contribution of coating microstructure to degradation and particle release in hydroxyapatite coated prostheses. , 63, 106-14. Guo, X. ; Yu, S. H. & Cai, G. B. (2006). A New controlled crystallization approach in a mixed solution using an artificial peptide type block copolymer as a crystal modifier: highly monodisperse CaCO3 microspheres and morphology control.
A,c,e,g,i) using (NH4)2CO3 as the CO32– source at 130 oC (except (c) at 150 oC); (b,d,f,h,j) using Na2CO3 as the CO32– source at 180 oC. (a,b) without an basic additive, (a) shows pumpkin-like morphology of aragonite phase of CaCO3, the insets of (a) show typical pumpkin-like morphology, scale bar = 200 nm, (b) shows cuboid-like morphology of calcite phase; (c,d) using urea, (c) shows a typical olive-like morphology of the aragonite phase, the inset of (c) shows a typical olivelike morphology, scale bar = 200 nm, (d) TEM micrograph showing the porous willow-leaflike morphology of the aragonite phase; (e,f) using hexamethylenetetramine (HMT), (e) shows a sphere-like morphology assembled from nanoparticles of the vaterite phase, the inset of (e) shows a typical assembled sphere, (f) shows cuboid-like morphology of calcite; (g,h) using ethylenediamine (EDA), (g) shows spherical nanoparticles of amorphous phase of CaCO3, (h) shows flower-like morphology of aragonite; (i,j) using NaOH, (i) shows the flake congeries of the vaterite phase, (j) shows cauliflower-like morphology of the calcite phase.
In future, the follow problems should be explored. For example, the relationship of properties and microstructure in biominerals; the intrinsic mechanism of biomineralization; the experimental examples for better understanding of the molecular recognition mechanism; how to simulate the biomineralization and realize biomimetic synthesis? 6. 2010CB732204) is gratefully acknowledged. 7. References Banfield, J. ; Welch, S. ; Zhang, H. ; Ebert, T. T. & Penn, R. L. (2000). Science 289,751-54. 44 Advances in Biomimetics Bastow, T.
Advances in Biomimetics by Anne George